DIOXIN96

16th Symposium on Chlorinated Dioxins and Related CompoundsAmsterdam, August 12-16, 1996

Organohalogen Compounds, Volume 28Short Papers

Editors: Kees Olie

Robert Louw

Jacob de Boer

Erik Evers

Heidelore Fiedler

Jan Hendriks

Ronald Hites

Narayanan Kannan

Djien Liem

Ross Norstrom

Michael Oehme

Mats Tysklind

Job van Zorge

UNIVERSITATSBI3LIOTHEKHANNOVER

TECHNISCHEiNFORMATIONSBIBLIOTHEK

UB/TIB Hannover115 350 586

89

Transport & FateEnvironmental LevelsToxaphenes, PCB's and other Non-Dioxins

TABLE OF CONTENTSVolume 28

Transport & Fate (FATE)

FATE ITransport & Fate

Wendy A. Lead, Jones K.C. (United Kingdom)The cold condensation & global fractionation hypotheses: The search forsupporting evidence 1

Harrie A.J. Govers, Krop H.B. (The Netherlands)Partition constants of chlorinated dibenzofurans and dibenzo-p-dioxins 5

Shin-ichi Sakai, Urano S., Takatsuki H., Shiozaki K., Gokita K. (Japan)Influences of humic acid and linear alkylbenzen sulfonate (LAS) on leachingbehavior of PCDDs/PCDFs from shredder residues 11

Noriyuki Suzuki, Yasuda M., Sakurai T., Nakanishi J. (Japan)M o d e l i n g t he p r o f i l e t r a n s f o r m a t i o n o f P C D D s a n d PCDFs in t h e e n v i r o n m e n t . . . 16

Michel Lebeuf, Gobeil C , Brochu C , Moore S. (Canada)Direct atmospheric deposition versus fluvial inputs of PCDD/Fs to thesediments of the Lower St. Lawrence Estuary 20

John Sandal Is, Berryman B., Bennett L, Newstead S., Fox A. (United Kingdom)Dioxins on land around a chemicals waste incinerator and assignment of source . . 25

Jianwen She, Hagenmaier H. (U.S.A.)Levels and rate of PCDD/Fs soil around Rastatt in Southwest Germany 31

Svetozar Polic, Leskovsek H. (Slovenia)Fate and transport of polychlorinated biphenyls (PCBs) between water andatmosphere of the polluted Krupa River in Slovenia 35

FATE IIFate Degradation

John Parsons, De Bruijne J.A., Goorissen H., Weiland A.R. (The Netherlands)Biogradation of chilorinated dioxins and dibenzofurans by thebiphenyl-utilizing strain JB1 39

Merel Toussaint, Van der Steen J., Parsons J.R., De Wolf J.,Beurkens J.E.M. (The Netherlands)Reductive dechlorination of chlorinated dibenzo-p-dioxins by abacterial consortium isolated from Lake Ketelmeer sediment 44

table of contents, p. 1

FATE (po)Transport & Fate (posters)

Patrik L. Andersson, Hagland P., Tysklind M. (Sweden)Rotational barrier of the polychlorinated biphenyls as a physico-chemicalparameter for use in modelling of QSARs and QSPRs 47

Claudia Bock, Harms H. (Germany)Metabolism of selected polychlorobiphenyl congeners in plant cell cultures 53

Ian T. Cousins, Hartlieb N., Teichmann C , Jones K.C. (United Kingdom)Volatilisations of polychlorinated biphensyls from sludge-amended soils 58

Satoshi Takada, Matsueda T., Kondo R., Sakai K. (Japan)Metabolites of 2,3,7,8-tetrachloro-and octachloro-dibenzo-p-dioxin, anddegradation of PCDDs and PCDFs in a fly ash sample by the White Rot FungusPhanerochaete sordida YK-624 64

Mats Tysklind, Andersson P.L., Strandberg B., Wagman N. (Sweden)Selection of PCBs for laboratory testing or use as indicators inenvironmental monitoring 68

Kerstin Welsch-Pausch, McLachlan M.S. (Germany)Pathways of atmospheric PCDD/F in a native grassland culture:The importance of particle-bound deposition 72

table of contents, p. 2

Environmental Levels

ENVI IEnvironmental Levels (General)

David H. Cleverly, Monetti M., Phillips L., Cramer P., Heit M., McCarthy S.,O'Rourke K., Stanley J., Winters D. (U.S.A.)A time-trend study of the occurrences and levels of CDDs, CDFs anddioxin-like PCBs in sediment cores from 11 geographically distributed lakesin the United States 77

Christoph Lau, Fiedler H., Hutzinger O., Rippen G., Wesp H.F., Sievers S.,Friesel P., Schacht U., Gras B., Reich T., Vahrenholt F. (Germany)Dioxin mass balance for the city of Hamburg, Germany. Part 1:Objective of the study and emission inventory 83

Peter Friesel, Sievers S., Fiedler H., Gras B., Lau C, Reich T.,Rippen G., Schacht U., Vahrenholt F. (Germany)Dioxin mass balance for the city of Hamburg, Germany. Part 4: Follow upstudy - trends of PCDD/PCDF fluxes 89

Thomas Webster, Connett P. (U.S.A.)Dioxin emission inventories: The importance of large sources 95

Hanspaul Hagenmaier, Walczok M. (Germany)Time trends in levels, patterns and profiles for PCDD/PCDF in sedimentcores of Lake Constance 101

Chris Rappe, Andersson R., Bonner M.S., Cooper K.R., Fiedler H.,Howell F.G., Lau C. (Sweden)PCDDs and PCDFs in municipal sewage sludge and effluent from theState of Mississippi, USA 105

Dennis J. Paustenbach, Wenning R.J., Mathur D., Luksemburg W. (U.S.A.)PCDDs and PCDFs in Urban Stormwater Discharged to San Francisco Bay,California USA 111

Erik H.G. Evers, Laane R.W.P.M., Groeneveld G.J.J., Olie K.(The Netherlands)Levels, temporal trends and risk of dioxins and related compounds inthe Dutch aquatic environment 117

ENVI IIEnvironmental Levels (Air)

Joseph Ferrario, Byrne C , Dupuy Jr. A.E. (U.S.A.)Coplanar polychorinated biphenyl (PCB) background contaminationin trace level analytical procedures 123

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Karen B. Riggs, Roth A., Kelly T.J., Schrock M.E. (U.S.A.)Ambient PCDD/PCDF levels in Montgomery County, Ohio: Comparison toprevious data and source attribution 128

Maximilian Swerev, Nordsieck H., Pawlik V., Hutzinger O. (Germany)Impact of emissions of modern waste incinerators on atmosphericconcentrations of PCDD and PCDF 134

Simon J. Buckland, Howard K.E., Salter R.T. (New Zealand)Assessment of the New Zealand environment for the levels ofPCDDs, PCDFs, PCBs and other organochlorine contaminants 140

Matthew Lorber, Braverman C , Gehring P., Winters D.,Sovocool W. (U.S.A.)Soil and air monitoring in the vicinity of a municipal solidwaste incinerator. Part II: Air monitoring 146

ENVI IIIEnvironmental Levels (Food)

Vernon J. Feil, Davison K.L., Tierman T.O., Anderson V.L. (U.S.A.)Distribution of polychlorinated dioxins and furans in beef 152

George F. Fries, Feil V.J., Davison K.L. (U.S.A.)The significance of pentachlorophenol-treated wood as a source ofdioxin residues in United States beef 156

Andrew A. Lovett, Foxall CD. , Creaser C.S., Chewe D. (United Kingdom)PCB and PCDD/DF concentrations in egg and poultry meat samplesfrom urban and rural areas in Wales and England 160

Arnold Schecter, Papke O., Dellarco M., Olson J. (U.S.A.)A c o m p a r i s o n o f d i o x i n s a n d d i b e n z o f u r a n s i n c o o k e d a n d u n c o o k e d f o o d . . . . 1 6 6

Rustem Z. Khamitov, Simonova N., Maksimov G., Maystrenko V.N. (Russia)Chlorinated dioxin and dibenzofuran levels in food from BashkortostanRepublic, Russia 171

ENVI (po)Environmental Levels (posters)

Abad E., Caixach J., Rivera J. (Spain)Analisys of PCDD/PCDF from emissions sources and ambient air inNortheast of Spain 1 75

Osomu Aozasa, Ikeda M., Nakao T., Ohta S., Miyata H., Huang C.-W.,Tsai H. (Japan)Air pollution by PCDDs, PCDFs and non-ortho coplanar PCBs in Japanusing pine needle as a biomonitoring indicator 181

table of contents, D. 4

Samuel Atuma, Linder C.-E., Bergh A., Wicklund-Glynn A., Andersson 6.,Johnsson H. (Sweden)Levels of selected coplanar PCBs in fish from the Swedish waterenvironment 187

Peter Behnisch, Engelhart A., Apfelbach R., Hagenmaier H. (Germany)Occurence of non-ortho, mono-ortho and di-ortho substituted PCBcongeners in polecats, stone martens and badgers from the state ofBaden-Wurttemberg, Germany 191

Keith R. Cooper, Bergek S., Fiedler H., Hjelt M., Bonner M.S.,Howell F.G., Rappe C. (U.S.A.)PCDDs, PCDFs and PCBs in farm raised catfish from southeastUnited States 197

Eckhard Denker, Alawi M.A., Buthe A. (Germany)PCB pattern in two fish species from the Gulf of Akaba, Jordan 203

Daniel Fraisse, Schnepp B., Mort-Bontemps C, Le Querrec F. (France)Levels of polychlorodibenzo-dioxins (PCDDs) andpolychlorodibenzo-furans (PCDFs) in milk in France 209

William Gillespie, Abbott J.D. (U.S.A.)Progess in reducing the TCDD/TCDF content of releases from bleachedpulp mills and fish taken below mill discharges 213

Jon Knutzen, Schlabach M. (Norway)Summary of data on toxicity equivalents from PCDF/PCDD and non-orthoPCB in marine organisms and sediments from Norway 219

Jutta Kohler, Peichl L. (Germany)Monitoring of PCDD/F with Kale 224

Edward A. Kruglov, Amirova Z.K., Loshkina E.A. (Russia)PCDDs and PCDFs in snow coat of an industrial city and as a result ofoil incineration at accident place 228

Yoichi Kurokawa, Matsueda T., Matayoshi N., Satoshi T., Kazumi F. (Japan)Distribution of polychlorinated dibenzo-p-dioxins and dibenzofurans invarious sizes of airborne particles 232

Christoph Lau, Fiedler H., Hutzinger O., Rippen G., Wesp H.F.,Sievers S., Schacht U., Friesel P., Gras B., Vahrenholt F. (Germany)Dioxin mass balance for the city of Hamburg, Germany. Part 2:Flux of PCDD/PCDF with liquid and solid wastes 237

Michel Lebeuf, Moore S., Brochu C. (Canada)The influence of PCBs and PCDFs in the sediments of Baie des Anglaison the Lower St.Lawrence Estuary 243

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Yvonne M. Liske, Kapila S., Spreng A.C., Schreiber R.J. (U.S.A.)An assessment of polychlorinated dibenzo-p-dioxins and furans in rawmaterials for cement production 249

Matthew Lorber, Braverman C, Gehring P., Winters D., Sovocool W. (U.S.A.)Soil and air monitoring in the vicinity of a municipal solid wasteincinerator. Part I: Soil monitoring 255

William J. Luksemburg, Mitzel R.S., Zhou H., Hedin J.H., Silverbush B.B.,Wong A.S. (U.S.A.)Polychlorinated dioxins and dibenzofurans in environmental samplesfrom China 262

Janina Lulek (Poland)Determination of polychlorinated biphenyls in waste motor andtransformer oils 267

Rainer Malisch (Germany)Dioxin-like PCB in food and breast milk samples 271

Rainer Malisch (Germany)PCDD/PCDF-intake from food in the South-Western part of Germany 277

Rainer Malisch, Saad M.M. (Germany)PCDD/PCDF in butter samples from Egypt 281

Wolfgang Moche, Thanner G. (Austria)Ambient air concentrations of dioxins in Austrian conurbations 286

Wolfgang Moche, Thanner G. (Austria)Ambient air concentrations of dioxins during stable weather conditions 291

Anders Olsson, Bergman A., Vitinsh M. (Sweden)Relative concentrations of PCB congeners in perch (Perca fluviatilis) asan indicator of fresh input of PCB near the Daugava river mouth in Latvia 295

Peter Rabl, Dumler-Gradl R., Thoma H., Vierle O. (Germany)PCDD/F-lmmission measurements in different distances from a emissionsource 300

Lourdes Ramos, Eljarrat E., Hernandez L.M., Alonso L., Rivera J.,Gonzalez M.J. (Spain)Levels of PCDDs and PCDFs in farm cow's milk located near potentialcontaminant sources in Asturias (Spain). Comparison with levels foundin control points and commercial pasteurized cow's milks 304

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Fabrizio Rodriguez, Carere C, Dell'Omo G., lacovella N.,Baldassarri L.T., Volpi F., Di Domenico A. (Italy)The Common Swift: A synanthropic bird species for monitoring airbornemicrocontaminants? 308

Takeo Sakurai, Suzuki N., Masunaga S., Nakanishi J. (Japan)Application of principal component analysis to isomer-specific datamatrix of PCDDs and PCDFs 314

Arnold Schecter, Cramer P., Boggess K., Stanley J., Olson J.R.,Kessler H. (U.S.A.)Dioxin intake from U.S. food: Results from a new nationwide food survey 320

Martin Schlabach, Biseth A., Gundersen H. (Norway)Sampling and measurement of PCDD/PCDF and non-ortho PCB in arcticair at Ny-Alesund, Spitsbergen 325

Marta Schuhmacher, Granero S., Domingo J.L., Rivera J., Eljarrat E. (Spain)Levels of PCDD/F in soil samples in the vicinity of a municipal solidwaste incinerator 330

Der-Kau Soong, Ling Y.-C. (Taiwan, ROC)Dioxin in soil samples at a chlorophenal manufacturing site in Taiwan 335

Terttu Vartiainen, Mannio J., Strandman T. (Finland)Concentrations of PCDDs, PCDFs and coplanar PCBs in fish fromsubarctic lakes in Finland 340

Monica Waber, Kohler J., Peichl L. (Germany)Polychlorinated biphenyl (PCB) contents in Curly Kale cultures inthe conurbation of Munich, Germany 344

Dwain Winters, Cleverly D., Lorber M., Meier K., Dupuy A., Byrne C ,Deyrup C , Ellis R., Ferrario J., Leese W., Schaum J., Walcott J.(U.S.A.)Coplanar polychlorinated biphenyls (PCBs) in a national sample of beefin the United States: preliminary results 350

table of contents, p. 7

Toxaphenes (TOXA)

TOXA IToxaphenes

Vladimir A. Nikiforov, Tribulovich V.G., Bolshakov S. (Russia)Structure-behaviour relationships for toxaphene congeners. I.Gas chromatography of chlorinated bomanes 355

Walter Vetter, Miiller U., Krock B., Luckas B. (Germany)Structures and GC retention times of persistent compounds oftechnical toxaphene (CTTs) 359

Jacob de Boer, De Geus H.-J., Brinkman U.A.Th. (The Netherlands)Multidimensional gas chromatographic analysis of toxaphene - testof different column combinations 363

Heidi Karlsson, Oehme M. (Switzerland)Comparison of retention time overlaps of toxaphene congeners on threedifferent stationary phases in cod liver samples and consequences forquantification 369

Mehmet Coelhan, Parlar H., Angerhofer D., Kimmel L. (Germany)A contribution to the HRGC-MS and HRGC-ECD determination of taxopheneresidues in fish 375

Gary A. Stern, Muir D.C.G., Billick B., Lockhart L., Wilkinson P.,Miskimmin B.M. (Canada)Toxaphene congener patterns in lake sediment 379

Vyacheslav G. Tribulovich, Nikiforov V.A., Bolshakov S. (Russia)Isolation and structure elucidation of polychlorodihydrocamphenes- potential constituents of toxaphene residues 385

Susan T. Glassmeyer, Myers T.R., De Vault D.S., Hites R.A. (U.S.A.)Taxophene in Great Lakes fish: A temporal, spatial and trophic study 389

TOXA IIToxaphenes

Deborah L. Swackhamer, Pearson R.F., Schottler S. (U.S.A.)A mass balance of taxophene in the Great Lakes of North America 395

Terry L. Wade, Chambers L., Gardinali P.R., Sericano J.L.,Jackson T.J., Allen-Gill S.M. (U.S.A.)Toxaphene analyses of fish livers by high resolution mass spectrometry 399

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Heidi Karlsson, Oehme M., Muller L. (Switzerland)Enantioselective separation of toxaphene congeners. Results,problems and challenges 405

Lutz Alder, Palavinskas R., Andrews P. (Germany)Enantioselective determination of toxaphene components in fish,monkey adipose tissue from a feeding study and human milk 410

Jan P. Boon, Helle M., Dekker M., Sleiderink H.M., Klamer H.J.,Govers B., Wester P., De Boer J., De Leeuw J.W. (The Netherlands)In-vitro biotransformation of chlorinated bornanes (toxaphene) inhepatic microsomes of marine mammals and birds. Influence onbioaccumulation and mutagenicity 416

Mahmoud A. Saleh (U.S.A.)Recent knowledge on the toxicological properties of toxaphene 422

TOXA (po)Toxaphenes and Other Non-Dioxins (posters)

Lutz Alder, Palavinskas R., Nikiforov V.A., Tribulovich V.G. (Germany)Relative response factors for toxaphene components using different detectors . . . 423

Lutz Alder, Karl H. (Germany)Determination of toxaphene (Camphechlor) residues in foodstuff 429

Kai Bester, Ellerichmann T., Hiihnerfuss H., Moller K., Rimkus G.,Wolf M. (Germany)On the presence of hepta- and hexachlorostyrenes in addition tooctachlorostyrene in fish samples from the river Elbe 433

Bianca Bethan, Bester K., Hiihnerfuss H., Rimkus G. (Germany)Contamination and gas chromatographic chiral separation of bromocyclenin water and fish samples from the river Stor in the northern part ofGermany and in some sewage plant's waste water 437

Rosa Dumler-Gradl, Langhojer J., Miekisch W., Tartler D., Thoma H.,Vierle O. (Germany)Solvolysis of flame retarded circuit boards 441

Jerzy Falandysz, Strandberg L., Bergqvist P.-A., Strandberg B.,Rappe C. (Sweden)Chloronaphthalenes in stickleback Gasterosteus aculeatus from thesouthwestern part of the Gulf of Gdansk, Baltic Sea 446

Jerzy Falandysz, Strandberg L., Strandberg B., Bergqvist P.-A.,Rappe C. (Sweden)Spatial distribution of chlordane compounds in plankton from thesouthern part of the Baltic Sea 452

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Lev A. Fedorov, Dostovalova V.I. (Russia)The prediction of NMR 13C chemical shifts for mixed Cl,Br-benzenesin frame of two-particel increments 456

Rauf V. Galiulin, Galiulina R.R., Bashkin V.N. (Russia)Predecessors of dioxins - DDT and PCBs in irrigated agrolandscapes ofRussia and Uzbekistan 459

Eva Jakobsson, Hu J., Marsh G., Eriksson L. (Sweden)Synthesis and characterization of twenty-eight brominated diphenyl ethers 463

Roland Kallenborn, Haugen J.-E., Nybe S. (Norway)Taxophenes and other organochlorines in dippers {Cinclus cinclus L.)from Southern Norway 469

Bernd Krock, Vetter W., Luckas B. (Germany)PCB - toxaphene group seperation on silica for interference freequantitation of toxaphene residues in environmental samples by GC/ECD 473

Lidia Strandberg, Falandysz J., Strandberg B., Bergqvist P.-A., Rappe C ,Kawano M., Tanaka Y. (Poland)Biomagnification of chlordane compounds by harbour porpoisePhocoena phocoena 478

Don T. Waite, Gurprasad N.P., Constable M.B. (Canada)Concentrations of pentachlorophenol and some related compounds inseasonally collected atmospheric samples from five Canadian locations 482

Kensei Yasuda, Shinoda K., Nakajima T. (Japan)Transchlorination between chlorinated benzenes and benzeneinto chlorobenzene 487

PCB'sMetabolites / Toxicity

Gerald Larsen, Feil V.J., Hakk H., Huwe J.K., Petroske E. (U.S.A.)Polychlorodibenzo-p-dioxin metabolism 491

Eva Klasson-Wehler, Jakobsson E., Orn U. (Sweden)Metabolism of polychlorinated naphthalenes and a tetrabrominateddiphenyl ether 495

Robert J. Letcher, Norstrom R.J., Muir D.C.G. (Canada)The bioaccumulation and metabolic formation of methyl sulfone PCBand 4.4'-DDE metabolites in the polar bear food chain 500

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Johan Lund, Andersson O., Barnes H.J., Gillner M., Hultenby K.,Hard T., Larsson C, Nord M., Nordlund-Moller L., Stripp B. (Norway)Structure and function of a clara cell secretory protein: A determinantof methylsulfonyl-PCB bioaccumulation 506

A. Gerlienke Schuur, Van Meeteren M.E., Jong W.M.C., Brouwer A.,Visser Th.J., Bergman A. (The Netherlands)Inhibition of thyroid hormone sulfation by hydroxylated metabolites ofpolychlorinated biphenyls in vitro 509

Yoshihisa Kato, Haraguchi K., Tomiyasu K., Saito H., Masuda Y.,Kimura R. (Japan)Evidence that 3-methylsulfonyl metabolite of 2,2',4,5,5'-pentachlorobiphenylis causative substance of induction of hepatic microsomal drug-metabolizingenzymes by the parent compound of rats 513

Pirn de Voogt, Van Raat P., Rozemeijer M., Green N. (The Netherlands)Methyl sulfonyl PCBs in cormorant chicks from the Netherlands 517

Cecilia Weistrand, Noren K., Grimelius L. (Sweden)Methyl sulphone metabolites of PCB and DDE in human adipose tissue and liver 522

NON-DIOX IBrominated Polyaromatic Compounds

Ulla Sellstrdm, Kierkegaard A., De Wit C, Jansson B., Asplund L.,Bergander L., Bignert A., Odsjo T., Olsson M. (Sweden)Polybrominated diphenyl ethers (PBDE) in the Swedish environment -a summary 526

Thomas Wanke, Vehlow J., Mark F.E., Brenner K.S. (Germany)The influence of flame retarded plastic foams upon the formation ofBr containing dibenzo-p-dioxins and dibenzofurans in a MSWI 530

NON-DIOX IIOther Halogenated Aromatic Coumpounds

Barbara R. Hillery, Hites R.A. (U.S.A.)Temporal trends in a long term study of vapor phase PCB concentrationsover the Great Lakes 536

Gary A. Stern, Tomy G.T., Muir D.C.G., Westmore J.B., Fisk A.T.,Cymblisty Ch.D. (Canada)Quantifying chlorinated n-alkanes in environmental samples by highresolution gas chromatography electron capture negative ion high resolutionmass spectrometry 540

table of contents, p. 11

Mats Tysklind, Elg K., Andersson P.L., Van Bavel B., Haglund P. (Sweden)The use of multivariate experimental design in the selection ofpolychlorinated naphthalenes for screening of biochemical andtoxicological effects 545

Ruth L. Stringer, Jacobs M.N., Johnston P.A., Wyatt C.L., Santillo D.(United Kingdom)Organochlorine residues in fish oil dietary supplements 551

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