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TABLE 4-2- .
SUMMARY OP RESULTS FOR TCLP ANALYSESSOURCE-AREA 2 WASTE MATERIAL(Concentrations in pg/L)
Parameter. Average
Concentration'11Maximum
Concentration'1'RegulatoryLimit'2'
VOLATILES
BenzeneCarbon Tetrachloride
Chloroform
1,2 Dichloroethane
Methyl Ethyl Ketone
TetrachloroethenaTrichloroethene
Total vocs
19
2.6
4.1
8.1
38
6.2
120
546
23
3.2
4.5
10
45
6.3
151
641
500
500
6,000
500
200,000
700
500__
SEMIVOLATILES
Total Semlvolatiles 663 748 - '_„
METALS •
Arsenic
Barium
Cadmium
Lead'"
50
350
5
11,000
, 60
410
10
11,000
5,000
100,000
1,000
5,000
Notes:
(1) Source is data for composite samples collected by Barr Engineering Co. andreported in Phase I immobilization treatability study report (Kiber,September 1992).
(2) From 40 CFR §261.24 (a).(3) Parameter exceeds regulatory limit.
38\06\001\DOUGSAR2.TAB\KMH3R303683
TABLE 4-3- ' - . - • • ' • ' • " * '
SUMMARY OF GENERAL CHEMICAL CHARACTERISTICSSOURCE AREA 2 WASTE MATERIAL
Parameter
TPH, %
Oil and Grease, %"- i
Total Organic Carbon, ppm
pH, standard units
Btu Content, Btu/lb
Sulfur, %
DataSource
A
B
C
A
B
A
B
A
B
C
B
C
Parameter Valve
Minimum
27
13
20
27
18 •"
4,700
3,600
•»•>
4.2
1.3
4,041
0.19
Maximum
33
36
47
30
36
6,200
130,000
w_
5.3
4.7
7,751
2 . 82
Average
31
21
37
29
26.5
5,333
46,400
3.0.
• ^mm
5,334
0.88
Data Sources:
(A) Treatability Study Composite Samples (Kiber, September 1992).(B) Phase II RI/FS (NUS, October 1988).(C) Thermal Treatability Testing Report Pre-Design Investigation (TAMS,
January 1992). ,v
38\0€\001\DOUGSAR2.TAB\KMH
TABLE 4-4
SUMMARY OF PHYSICAL CHARACTERISTICSSOURCE AREA 2 WASTE MATERIAL
• .
Parameter
Bulk Unit Weight, pcf
% Sand
% Fines
Permeability, cm/s
% Moisture
DataSource
• ' A
B
B
A
A
3
Parameter Valve
MinimumValue
33.3
- 10.4
63.1
7.63-03
23
17
MaximumValue
33.3
31.9
89.6
5.6E-07
23
30
AverageValue
83.3
17.9
81.9
3.2E-07
28
24
Data Sources: •\
(A) Treatability Study Composite Samples (Kiber, September 1992).(B) Thermal Treatability Testing Report Pre-Design Investigation (TANS,
January 1992). ,
38\06\001\DOUGSAR2.TAB\KMH
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4R303686
TABLE 8-1
SUMMARY OF POTENTIALLY APPLICABLE OR RELEVANT AND APPROPRIATE REQUIREMENTS
Law or Requirement General Application
FEDERAL LAUS
Resource Conservation and Recovery Act Requirements for the identification, generation,(RCRA) 42 U.S.C. §§6901 to 6991 i transport, 'treatment, storage and disposal of
hazardous waste. Requirements for disposal of solid•- ' waste. • . •
Clean Water Act (CUA) . • Primary purpose is the restoration and maintenance of33 U.S.C. §! 1251 to 1387 the integrity of nation's water. CUA regulations most
pertinent to CERCLA sites include requirements forsurface water quality, direct discharge to surfacewaters, discharges to publicly owned treatment works,and discharges of dredge-and-fill materials intosurface waters.
Safe Drinking Water Act (SDUA) . Protection of public/community drinking water42 U.S.C. §§ 300f to 300J-11 supplies. Underground injection program.Clean Air Act-(CAA) , . Objective is the protection and enhancement of the42 U.S.C. §§ 7401 to 7642 quality of the nation's air resources. Applicable to
mobile and stationary sources.Toxic Substance Control Act (TSCA) Establishes testing, premanufacturing notification,15 U.S.C. §§ 2601 to 2654 control, and recordkeeping regulations pertaining to
• toxic chemical substances. Includes requirementsgoverning PCBs and asbestos.
Federal Insecticide, Fungicide, and Regulates the sale, distribution, and use of allRodenticide Act (FIFRA) pesticide production in U.S. through product licensing7 U.S.C. i 136 to 136y or registration.
National Historic Preservation Act Protection of properties as cultural resources.16 U.S.C. 470
Endangered Species Act - ' Requirement that federal agencies consult with DO! arid16 U.S.C. § 1531 to 1544 NOAA to ensure that their actions are not likely to
jeopardize the continued existence of endangered orthreatened'species or habitat.
Wild and Scenic Rivers Act (WSRA) Requirements that apply to water resource projects16 U.S.C. 1271 " affecting wild, scenic, or recreational rivers within
the National Uild and Scenic Rivers System.Fish and Wildlife Coordination Act Protection of fish and wildlife when federal actions16 U.S.C. 661 control or modify a natural stream or body of water.Coastal Zone Management Act (ZMA) Regulates actions by federal agencies that directly16 U.S.C. §§ 1451 to 1464 ' affect thai coastal zone. Requires federal agencies to
conduct or support their activities in a mannerconsistent with approved stats coastal zone management.programs. . . . . '
Wilderness Act Administers wilderness areas to preserve their16 U.S.C. 1131 character to keep them unimpaired for future use as
wilderness.Coastal Barriers Act Protects and maintains a system of Coastal Barriers16 U.S.C. 3501 Resources System.Uranium Mill Tailings Reduction Act Provide stabilization, disposal, and control of42 U.S.C. § 7901 to 7942 residual radioactive materials at designated uranium f ~~~-
processing depository sites. , . ' ,
Surface Mining Control and Reclamation Act Protection of human health and the environment from ""30 U.S.C. §! 1201 to 1328 • adverse effects of surface coal mining operations.
33\06\001\DOUGSAR2.TAB\KMH
AR303687
TABLE 8-1 (Continued)
SUMMARY OF POTENTIALLY APPLICABLE OR RELEVANT AND APPROPRIATE REQUIREMENTS
Law or Requirement . «'. ' General Application
Occupational Safety and Health Act • Protection of worker safety.29 U.S.C. 651
Hazardous Materials Transportation Act Regulation of interstate and intrastate.(HMTA) -
National Environmental Policy Act, (NEPA) . Ensures the consideration of the environmental42 U.S.C. § 4321 to 4370b ' consequences of federal actions.
Executive Order for Flood Plains (EO , Reviews federal actions in flood plains.11988)
Executive Order for Wetlands (EO 11990) Reviews federal actions in wetlands.
Migratory Bird Act Treaty . Protects habitat of migratory birds.Anadromous Fish Conservation Act Protection of anadromous fish.
National Wildlife Refuge System Protection of wildlife refuges.Administration Act '
Marine Mammal Protection Act • Protection of marine mammals.16 U.S.C. 1361 .
Archaeological and Historic Preservation Preservation of historical and archaeological data.A c t ' • • " . • • . ' . . - • ' . •16 U.S.C. 469 ,
PENNSYLVANIA LAWS ; •
Solid Waste Management Act, Act 97 Standards and requirements governing solid and35 P.S. 601S.11 et seq. . hazardous waste disposal.Clean Streams Law , Standards governing water quality.PL 1987, as amended. 35 P.S. 691.1 ct seq. .
Pennsylvania Safe Drinking Water Act > Community/public water systems.PL 206, 35 P.S. 726.1 et seq.
Air Pollution Control Act ' . Standards governing air quality.PL 2119. 35 P.S. 4001 et seq.
Floodplain Management Act . • Regulation of activities within the 100-yearPL 851. 32 P.S. 679.101 et seq. floodplain.Stormwater Management Act Requires municipalities to prepare stormwaterPL 864, 32 P.S. 680.1 et seq. management plans.
Pennsylvania Scenic Rivers Act Establishment and protection of state scenic rivers.PL 1277, 32 P.S. 820.21 et seq.
38\06\001\DOUGSAR2.TAB\KMH
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TABLE 8-3
NATIONAL AND PENNSYLVANIA AMBIENT AIR QUALITY STANDARDS
POLLUTANT
Carbon Monoxide
Ozone
Nitrogen Oxides
Participates (PM-10)
Sulfur Dioxide
Lead
Settled Particulate
Beryllium
Sulfates (ab H2 S04)
Fluorides
Hydrogen Sulf ide
TIME
8-hr1-hr
a. a. in*
a.a.m24-hr
a.a.m24-hr
a.a.m
i-yr30-day
30-day
30-day24-hr
24-hr
24-hr1-hr
FEDERALPRIMARY
9 ppm35 ppm
,0.12 ppm
0.05 ppm
50 fig /to*150 i/g/m1
0.03 ppm0 . 14 ppm
1.5 yg/m3
•. ~
/ —
•>•
.
FEDERALSECONDARY
9 ppm35 ppm
0.12 ppm
0.05 ppm
. 50 Itg/tt?150 yg/m3
..'.""".
1,5 pg/m3
'. — •
. • • »
''
•••.
~
PENNSYLVANIAPRIMARY
9 ppm35 ppm
0.12 ppm
0.05 ppmV
50 Aig/m*150 pg/m1
0.03 ppm0.14 ppm
1.5 yg/m3
0.8 mg/cm2/mo1.5 rag /era2 /mo
0.01 ^g/m3
10 pg/mj30 A/g/m3
5 pg/m3
0.05 ppm0.1 ppm
PENNSYLVANIASECONDARY
9 ppm35 ppm
0.12 ppm
0.05 ppm
50 jjg/m3150 yg/m3
• ' • . ' — .
1.5 g/m3
. ,'
«.«.
'• . • —
^
1 —
.* a.a.m. * annual arithmetic mean
38\06\001\DOUGSAR2.TAB\KMHJIR303692
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Treatment and
prohibited in
agricultural
-aestablished un
Area Security
farmland class
Class
1 agricu
land by SCS.
I2I
l1sis
be designated
tional value.
is
Treatment or
prohibited.
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1
1
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a:
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CONCERN
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ll
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llill
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fe£f*fe .~- at fr£•» |c m! -fell •ui E <S
tl
tment end disposa
vities; demonstra
design can
stand seismic
vities.
HillL.It
8*a
Uithin 5 mil
earthquake e
f1
. «»*
^
'•* •»«u u .
No evidence o
potentially a
within 1
mile
i.?. •'
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"•
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1i"?
' ""?
IT;CO. •••
osal prohibited
ss demonstration
that unit
isgned to withstand
t activity.
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tainers.
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igni ta
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nust naintain a 40
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« LOCATION-SPECIFIC
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If.c <o$*S"i
I
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en >c ' > «; e —
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River
listed as
1-A
priority for study as a
state wild, scenic,
recreational,
pastoral,
or modified recreational
river.
•«
l51*IHto o
it1
SQ
> ^Bk
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o « —
ife
ate
pal
rk
facility,
picnic a
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par
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onal
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ty, tio
for
egh
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par
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i
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of adverse
al,
visual
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c
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lothe
trai
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•8"
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nn to
life
ed by er ted
ta
ional
Natur
dnark designa
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^S-Sfeio*. e-i« *-es-r ^*!*«i» «:« «*;«
or by
i «'fe
oin
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kl
l- »- E
t» -•2
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ldlife
ional
fish
national
al center
ed by FUS
i wi at or
enti
iona
uge,
cher
iron
rate
Pot
nat
ref
hat
env
01
f a
cece
oin
Of*> ua.> a.10
ii
!i|I- H- E
"o To
toric property owne
the Historical a
ndonnission
Hi by
fl-R'3 03.705
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TSe
S.Efe£
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toric site listed
ional Register of
torical l
Hi Na Hi
o H0 °H
01
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TABLE 9-1- . ' - " ' • ' '
CONTAMINANTS SHOWING STATISTICALLY SIGNIFICANT DECREASES OVER TIME' ' . ' • - . ' • ' ' . ' ' • • • !
BSI TREATABILITY STUDY
Compounds
SVOCs:Benzo ( a ) anthracene
VBenzo (g,h,i)peryleneChryseneFluoranthene2 -Methy InaphthaleneNaphthalenePhenanthreneVOCs:
Acetone2-Butanone •ChloroformEthyl BenzeneTetrachloroetheneTolueneTrichloroetheneTotal Xylenes
PCBsAroclor-1260
, Bulk Pollutants3:Total Oil and GreaseTPH
With Surfactant.Statistical
Test1
• ' • .SignificantSignificantSignificantSignificant •
. SignificantSignificantSignificant
SignificantInsignificantSignificantSignificantSignificantSignificantSignificantSignificant
Significant
SignificantSignificant
ReductionPercent2
»
90898890506146
782394719883
. 8169
52
' 3529
Without SurfactantStatistical
Test1
SignificantSignificantSignificantSignificantSignificantSignificantSignificant'
SignificantSignificantSignificantSignificantSignificantSignificantSignificantSignificant
Significant
SignificantSignificant
ReductionPercent2
90906688505840
62
589455607284
49
48
3248
\J
Statistical test of significant differences between time zero concentration andfinal measured concentration are based on a comparison of LSD values, where LSD =
t,,.,, (2 x MSE/3)1". See Appendix B. Douglassville Treatability Study -Final Report(Bioremediation Services/ Inc., May 1993).
'Reduction Percent « [(Average initial concentration . - average final'concentration)/{average initial concentration)J x 100. Anomalous observations weredeleted from calculation.
- . , ' ' \ ' - ' , , - ' _ • • _ . ' •
'Regression analysis of decreases over time indicate that statistically significantdecreases in contaminant concentrations occurred during the first 10 weeks of the BSIstudy.
38\06\001\DOUGSAR2.TABXKMHAR3Q3733
TABLE 9-2
CONTAMINANTS IN TCLP EXTRACTWITH STATISTICALLY SIGNIFICANT DECREASES OVER TIME w.
BSI TREATABILITY STUDY
Compounds
TCLP-LeadTCLP-SVOCs:Bis(2-chloroethyl)ether1 , 2-D i ch I orobenzene2 ,4-D imethy I pheno IIsophorone .2-Methylnaphthalene2-Methylphenol
4-MethylphenolNaphthalenePhenol
TCLP-VOCs:
AcetoneEthyl Benzene4-Methy 1 - 2- pentanone
Toluene •TrichloroetheneTotal Xylenes
With Surfactant
StatisticalTest1
Significant
Significant
SignificantSignificant
InsignificantInsignificantSignificantSignificantInsignificantSignificant
SignificantSignificantSignificantSignificantSignificantSignificant
. ReductionPercent2
55
91
9679
30239997
3999
68
9893
989899
Without SurfactantStatistical
Test1
. Insignificant
Significant
SignificantSignificantSignificantInsignificantSignificantSignificantInsignificantSignificant
SignificantSignificantSignificantSignificantSignificantSignificant
ReductionPercent1
14
87
9786
. 56519999
4699
80
9980
9799
100
'statistical test of significant differences between time zero concentration and final measured concentrationare based on a comparison of ISO values, where LSD * ttat (2 x MSE/3)*, See Appendix 3. Oouglassville TreatabilityStudy - Final Report (Bioremediatlon Services. Inc., Nay 1993).
'Reduction Percent • [(Average initial concentration - average final concentration)/(averagt initialconcentration)] x 100. x ;
38\06\001\DOUGSAR2.TAB\KMH
aR.30.373l»
TABLE 9-3
SUMMARY OF CALCULATED FIRST ORDER DEGRADATION CONSTANTSBSI TREATABILITY STUDY'
• ' • . '•n V R' Stat. Test
k(I/week)
k(1/day)
t,,(day)
Acetone • . . < • . . ' -A:AC:B:BC:
lnC-7.57-0.813TlnC-6.78+0.127TlnC-7.54-0.524TlnC-7.08-0.020T
9999
0.440.510.700.86
0.750.050.320
significantInsignificantinsignificantinsignificant
0.813..
- •--• .
0.116— '....
6.0..
, • *
...2-Butanone
A:AC:
B:BC:
lnCs8.00-0.124TlnC«7.50+0.143TlnC-8.36-0.406TlnC-8.34-0.190T
9999
0.450.670.560.30
0.060.040.310.26
insignificantinsignificantInsignificantinsignificant
.. '
..• i.'.-
...
..
..i.
..
..
..•' -,
Chloroform ' • 'A:AC:B:BC:
lnC-4.42-1.413TlnC-4.49-1.455TlnCx4.42-1.402TlnC-4.33-1.137T
9999
0.450.480.460.80
0.890.890.890.64
significant. significantsignificantsignificant
1.4131.4541.4021.137
0.2020.2080.2000.162
3.43.33.54.3
Ethylbenzene •• ,
A:AC:B:BC:
lnC-6 85-0.629TlnC*6.94-0.268T
lnC-6.95-0.408TlnC-7.26-0.201T
99
99
0.210.24
0.220.18
0.890.51
0.750.51
significantsignificantsignificantsignificant
•0.629
0.2680.4080.201
8.99x6*3.83x10'
5.83X10'12.87x10'
7.718.111.924.1
Tetrachloroethene ' -A:AC:B:BC:
TolueneAcAC:
B:BC:
lnC-5.76-2.027TlnC-5.42-0.125TlnC-5.56-0.466TlnC-5.B1-0.233T
lnC*6.42-0.884TlnC-6.58-0.452TlnC-6.63-0.657T
lnC-6.90-0.333T
8998
9999
0.710.440.230.20
0.320.320.350.42
0.890.060.780.58
0.870.64
0.750.35
significantinsignificantsignificantsignificant
significantsignificantsignificant-significant
2.027..
0.4660.233
0.8840.4520.6570.333
0.290..
6.66x10*3.33x10'
0.1266.46x10-*9.39x10'*4.76x10-'
2.4...
10.420.8
5.510.77.414.6
Trichloroethene • .A:AC:B:BC:
lnC-6.02-0.872TlnC-6.16-0.775TlnC-6.35-0.946TlnC-6.59-0.599T
7989
0.300.290.380.24
0.890.860.860.84
significantsignificantsignificantsignificant
0.8720.7750.9460.599
0.1250.1100.135
8.56x10*
5.66.35.18.1
38\06\001\DOUGSAR2.TAB\KMH3R3G3735
TABLE 9-3 (Continued)
SUMMARY OF CALCULATED FIRST ORDER DEGRADATION CONSTANTSBSI TREATABILITY STUDY
n Sl> R' Stat. Testk
(1/week)'k.
(1/day)t»
(day)
Xylenes . ' . ,
A:AC:8:
BC:
lnC=8.42-0.577TlnC-8.53-0.209TlnC-8.51-0.333T
lnC-8.87-0.171T
999
9
0.180.310.180.18
0.89
0.280.750.43
significantinsignificantsignificantsignificant -
0.577..
0.333
0.171
8.24x10*•
4.76x10*2.44x10'*
3.4'
14.623.4
Benz(a)anthracene < , . - . ' • ' •A:
AC:B:BC:
inC-9.39-0.179TlnC-9.22-0.189TlnC-9.41-0.183TlnC=8.79-0.155T
9"696
0.630.120.540.25
0.740.990.810.96
significantsignificantsignificantsignificant
0.1790.1890.1830.155
2.56X10-12.70x10-'2.61x10-'2.21x10''
27.1
25.726.531.3
Benzo(3hi)perylene • ,,A:AC:
.. B:BC:
lnC-8.50-0.155TlnC-9.02-0.174TlnC-8.59-0.163TlnC=8.68-0.147T
8684
0.450.080.47
0.03
0.801.00
0.80
1.00
significantsignificantsignificantsignificant
0.1550.174
0.1630.147
2.21x10*2.49x10*2.32x10*2.10x10''
31.327.929.833.0
•,Chrvsene
A:
AC:B:BC:
lnC-9.24-0.159TlnC-9.46-0.155TlnC-9.02-0.138TlnC-9.36-0.146T
9686
0.410.110.370.04
0.840.990.83
1.00
significantsignificantsignificantsignificant
0.1590.1550.1380.146
2.27x10-'2.21x1ff'1.97x10'
2.09x10''
30.531.335.2
33.2Muoranthene ' - ' .
A:AC:B:BC:
lnC-9.18-0.177TlnC-8.99-0.172TlnC=9.05-0;167TlnC-8.89-0.163T
9
596
0.330.11
0.290.07
0.91
0.99
0.921.00
significantsignificantsignificantsignificant
0.177
0.1720.167 .
0.163
2.53x10'2.46x10-' '
2.39x10-'2.33x10-'
27.4
28.229.1
29.82-Methylnaphthalene
A:AC:
B:BC:
lnC-10.77-(5.20x10aTlnC»10.80-(4.8x1<r')T
lnC»10.79-(5.35x10-')TlnC-11.02-(3.68xia')T
96
96
0.170.19
0.210.09
0.780.80
0.700.91
significantsignificantsignificantsignificant
5.20x10-'4.80x10-'5.35x10-'3.68x10'*
7.43x1046.86x10*
7.64x1045.26x104
93.3101.1
90.7131.8
Naphthalene ' •A:AC:B:BC:
lnC»10.41-(7.00x10'')TlnC-10.50- (5.75x10 *>TlnC-10.34-(6.76x10-*)T
lnC»10.69-(3.74x10-')T
969
6
0.210.230.260.11
0.310.800.720.87
significantsignificantsignificantsignificant
7.00x10-*5.75x10-*6.76x10-*3.74x10-*
1.00x10-'
8.21xKr*9.66x10-*5.34x104
69.384.471.8129.7
33\06\001\DOUGSAR2.TAB\KMH „ « ,-SR303736
* TABLE 9-3 (Continued) 5
SUMMARY OF CALCULATED FIRST ORDER DEGRADATION CONSTANTS\ / BSI TREATABILITY STUDY
R
• ,n Sfr R* Stat. Test
fc(1/week)
k(I/day)
t*(day)
Phenanthrene
A:AC:
B:
BC:
lnC-10.12-(4. 38x10 *)TlnC-10.12-(4.87x10')T
lnC=9.93-(1. 00x10 *)T
lnC«10.20-(3.71x10-')T
969
6
0.250.200.25
0.15
0.530.790.47
0.80
significantsignificantsignificantsignificant
4.38x10*4.87x10*4.00x10*
3.71x10*
6.26x10*6.96x10*5.71x10
5.30x10J
no. B99.6
121.3130.8
Aroclor-1260 • . , • . •
A:AC:B:BC:
lnC«10.69-(8.28x10-')TlnC»10.69-0.158TlnC»10.79-(4.63x104)TlnC*11.46-0.138T
969
6
0.70
1.230.621.42
0.34
0.510.170.37
insignificantinsignificantinsignificantinsignificant
-. - -•
-
..
' - .
- \
•-.
- '
number of observationsstandard error of estimation .
square of correlation coefficient ' . .first order reaction constant 'estimated half-life ,statistical significant based on comparison of 90 percent confidence level of the correlation coefficientR for a sample of size n, degree of freedom * n-2 (see Snedecor, G.U. and Cochran, W.G., 1980).
38\06\001\DOUGSAR2.TAB\KMH •
TABLE 9-4
STATISTICAL COMPARISON OF FIRST-ORDER DEGRADATION RATE CONSTANTSFOR THE ACTIVE AND CONTROL REACTORS
BSI TREATABILITY STUDY
Compound
AcetoneChloroformEthylbenzeneTetrachloroetheneTolueneTrichloroetheneXylenes
Benzo(o)anthraceneBenzo(ghi )peryleneChryseneFluoranthene2-HethylnaphthaleneNaphthalenePhenanthrehe
Treatment Ak
(1/ueek)
0.8131.4130.6292.0270.8840.3720.577
0.1790.1550.1590.1770.0520.0700.044
s,0.1780.1850.084JL2880.1290.1370.075
Treatment ACk
(1/ueek)
-0.1271.4550.2680.1250.4520.7750.209
0.0400.0310.026JL0210.0100.0130.016
0.1890.1740.1550.1720.0480.0570.049
s»0.2070.1950.0990.1780.1290.1160.127
0.0070.0050 0070.0080.0120.0140.013
_t
> 3.44-0.16
2.785.712.370.542.49
-0.22-0.580.130.210.260.69-0.24
t.M
JL351.351.351.35JL351.351.35
1.361.371.361.371.361.361.36
Test Result
significantInsignificantsignificantsignificantsignificantinsignificantsignificant
insignificantinsignificantinsignificantinsignificantinsignificantinsignificantinsignificant
Compound
ChloroformEthylbenzeneTetrach loroetheneTolueneTrichloroetheneXylenes
Benzo(o)anthraceneBenzo(ghi )peryleneChryseneFlburanthene2-MethylnaphthaleneNaphthalenePhenanthrene
Treatment Bk
(I/week)
1.4020.4080.4660.6570.9460.333
0.1830.1630.1380.1670.0540.0630.040
s»MST
0.08980.0930.144JL1540.073
0.034JL0330.0260.0180.013JL0160.016
Treatment BCk
(I/week)
1.1370.2010.2330.3330.5990.171
0.1550.1470.1460.1630.0370.0370.037
s»0.3250.0740.0810.1720.0990.075
0.0150.0020.0030.0040.0060.0070.009
/
t
0.711.781.881.441.931.55
0.690.35-0.300.191.141.620.10
t.»
1.351.351.351.351.351.35
1.361.401.371.361.361.361.36
Test Result
insignificantsignificantsignificantsignificantsignificantsignificant
insignificantinsignificantinsignificantinsignificantinsignificantsignificantinsignificant
k » first order reaction constant (I/week) . . . . . .st.» standard error of the k value ' . " . " " ' ' /' .t - calculated t value of differences between the first-order reaction constants of the active and — ' i
control reactors " . , V Jtut* critical t value based on df=n,+n,-4 at 0.20 significant level "
38\06\001\DOUGSAR2.TA3\KMH s r> 1 D Q^R303738
TABLE 9-5
SUMMARY OF IMMOBILIZATION TREATABILITYTESTING RESULTS FOR THE IWT PROCESS
Parameters or Characteristic
TCLP Lead (mg/L)MEP Lead (mg/L)
Total PCBs (mg/kg)Total' Volatiles (mg/kg)'J|TCLP Volatiles (yg/L)(J|Total Semivolatiles (mg/kg)131TCLP Semivolatiles (jig/L)»J>TPH ( % )
Permeability (cm/s)Unconfined CompressiveStrength ,Freeze/Thaw Testing MassLtld (%)
CS5 :Wet/Dry Testing Mass Lead(*)
Untreated Filter Cake'"Maximum
11. s
71
43641
93
748
335.6 x ID'7
. ; '--'
— •
•'•-•• — '. •
Average
11—
34
39540
80
668
313.2 x ID'7.
• — .
— •
Treated Filter Cake'2'Maximum
<0.019<0.01920.2
29.5397
89
541
20
7.1 x 10-7216.9
<1.0
<1.0
Average
<0.019<0.01918.529.1296
89532
204.6 x 10-7165.5
<1.0
<1 . 0
(1) Data summarized in Tables 4-1 through 4-4 for Barr composite samples used in thetreatability study. Three samples were analyzed except for MEP (10 samples),UCS (6 samples), permeability (2 samples).
(2) Data reported in the Douglassville Treatability Study Synopsis Report (Kiber,June 1993) (2 samples). Results have not been corrected for a 50 percentdilution resulting from the treatment process.
(3) Calculated as the sum of reported concentration assuming zero for compounds notdeleted. Lower detection limits for treated filter cake result in a largernumber of reported detection.
38\06\001\DOUGSAR2.TAB\KMH fl D 1 O "7 O O
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I • ' ' "sc 1 |N FEET———'' * Pre-Deslgn Investigation (TAMS. Jan. 1992)• Barr Field Sampling Event (Barr, July 1992)
BarrEngineering Company
r^ • •'••• - Figure 4—4DouglassvilleDisposal Site SOURCE AREA 2 SAMPLING ANC______ CROSS-SECTION LOCATION MAP
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Retained AlternativesDevelopRemedialAction
Objectives Prepare ConceptualDesigns and
Cost Estimates forRetained Alternatives
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App'ly EvaluationCriteria To Retained
AlternativesIdentifyPotential
Technologies
Rejected^ TechnologiesScreen
Technologies UsingAbility To Meet Remedial
Objectives andImplementability
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FurtherAnalysis
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Record ofDecision
NoFurtherAnalysisIdentify
Process OptionsFor EachTechnology
RejectedProcessOptions
SelectedRemedy
NoFurtherAnalysis
Screening Criteria ToTechnology/Process
Retain OneRepresentative ProcessOption Per Technology
Develop Comprehensive Remedial Alternatives for Site(Or Portion of Site) From Retained Technologies/Process Options
Rejected_ AlternativesApply
Screening Criteria ToAlternatives
NoFurtherAnalysis
(Reference: USEPA, October 1988)
WL BarrEngteerhg Company
•* , .,, Rgure'5-1DouglassvilleDisposal Site SUMMARY OF CERCLA
ALTERNATIVES ANALYSIS PROCESS
aR303787
SCREENING CRITERIA NINE EVALUATION ROLE OF CRITERIACRITERIA DURING REMEDY
SELECTION
Effectiveness
Implementability
Cost
(Source: USEPA, October 1988)
Overall Protection of HumanHealth and Environment
Compliance with ARARs
Reductions in Toxicity, Mobility,and Volume Through Treatment
Implementability
Cost
Community Acceptance
> "Threshold" Criteria
Short-term Effectiveness"Primary Balancing" Criteria
State Acceptance
"Modifying" Criteria
BarrEngineering Company Disposal Site
_ . . . , . Figure 5-2Dpuglassville •RELATIONSHIP OF SCREENING CRITERIATO THE NINE EVALUATION CRITERIA
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-
.; . . •
. Long-termEffectiveness
andPermanence
• Magnitude ofResidual Risk
• Adequacy andReliability ofControls
. • " - . • ' ' .
- . . .
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•
,• • •Compliance
withARARs
- *
• Compliance withChemical-Specific ARARs .
• Compliance with. Action-Specific ARARs
• Compliance with . .Location-Specific ARARs
• Compliance with OtherCriteria, Advisories, and >Guidances
iess Implementability Cost• - ... '
• Treatment Process • Protection of • Ability to Construct • Capital Costs- Used and Material Community During and Operate the • Operating and •
Treated Remedial Actions Technology Maintenance Costs• Amount of Hazardous • Protection of Workers • Reliability of Present Worth Costs
Materials Destroyed During Remedial Technologyor Treated Actions .... Ease of Undertaking
• Degree of Expected * Environmental Additional Remedial»I .,rt5nne inTVwirW tnpacls Actions, If NecessaryReductions taToxidty, , Tune Until Remedial • Ability to MonitorMobility, and Volume • • . .. _.. . _« ' ,. « __ \_ ..«.=.!. Acbon Objectives are Effectiveness of . , - .
x. •
•
(Source: USEPA, Octal
BurrEngineering Company
• i cicrcc iw wmwn « .1 * .0 AauevedTreatment is •Irreversible
• Type and Quantity ofResiduals RemainingAfter Treatment
. - . , \
: 1 ' '
, State Acceptanc
3erl988) "'; ————————
DouglassvilleDisposal Site
Remedy .• Ability to Obtain
Approvals from . , .Other Agencies
• Availability of Off-Site Treatment,Storage, andCapacity / ,
• Availability of /NecessaryEquipment andSpecialists
• Availability ofProspectiveTechnologies
CommunityAcceptance
1
Figure 5-3'EVALUATION FACTORS FOR DETAILED
ANALYSIS OF ALTERNATIVES
AR303789
MATERIALS PROCESSING RESIDUALS
Source Material Ml ^ Excavation
———————>• Water^ To Excavation Pit
—————> Source Material^ To Stockpile
For PrimaryTreatment
R3—————— > Oversize (6") DebrisWater.R4 Landfill
: —— "••, Washwater" To Wastewater
Treatment
BarrEngineering Company
DouglassvilleDisposal Sitei ' i
Figure 10-1 -WASTE EXCAVATION AND PROCESSINGCONCEPTUAL PROCESS FLOW DIAGRAM
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MATERIALS PROCESSING RESIDUALS
Ml
Fuel
VibgtagBar I Rl » Oversize (2") Rocks^ToRockWasher
————————— _ ——
PI^ f
Incinerator
Water ________________I———'——~J—————————————y rjUS
• To Atmosphere
Nonhazardous AshTo On-Site Landfill
WaterWaste Water
Treatment
Stabilization ReagentsWater . „ _ . fc .Reject Based on
PerformanceCriteria-
Stabilized Material^ To On-Site Landfill
i ••! Figure 10-5DouglassvilleDisposal Site INCINERATION CONCEPTUAL
PROCESS FLOW DIAGRAM
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MATERIALS PROCESSING RESIDUALSProcessing Tents
Source Material——m————--——————* Vib _Bax | tR1 > Oversize Rocks, debris, > To Rock Washer
Straw(Bulking Agent)
MicrobesNutrientsHydrogen PeroxideSurfactant •
HighspeedMixing
Cleaned Air^ To Atmosphere
Cleaned Air' To Atmosphere
Treatment Residue^ TO On-Site LandjW
BarrEngbeenng Company B p
_ , .„ Rgure10-7DouglassvilleDisposal Site felOREMEDIATION CONCEPTUAL
PROCESS FLOW DIAGRAM
aococoWto
MATERIALS PROCESSING RESIDUALS
Source Material—————^————> viugm^Dar | Ri______^ Oversize (2") RocksTo Rock Washer
**~ Reject Based onPerformance Criteria
Reagenttreated Material
Barr.Engineering Company Disposal Site
_ , .„ Rgure10-9DouglassvilleiT"* .* ^ ' A j *4*« IMMOBILIZATION: MODERATE COST SCENARIO
CONCEPTUAL PROCESS FLOW DIAGRAM
AR303798
MATERIALS PROCESSING
Source Material ——— — — —— —— >• Bar"8 1Screen 1
• , .-..'• . • ' ... ' .w '-- ' • ' ' . • ' • i ' '
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w_ _ t M3 . HjghShear ' |Reagent— ——— —— —— > PugMOl 1 ——Wfl.tcr B T
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. . .' , • . . '
•
I?fII*r Douglassville^ SA Disposal Site IMMC
RESIDUALS
R1 ' > Oversize (2") Rocks^ To Rock Washer
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- . . • ' '
rmiU
RejectBasedOn PerformanceCriteria .
P4
—————— Treated Material*& To On-Site Landfill
Rgure 10-10)BILIZATION: HIGH COST SCENARIO:EPTUAL PROCESS FLOW DIAGRAM
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